Circular of the Bureau of Standards, Tema 524U.S. Government Printing Office, 1953 |
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absolute acid activity coefficient AgNO3 anode approximately aqueous solutions Bockris boundary Bureau of Standards calculated capillary cathode CdSO4 charge Chem chloride Clark cell conductance cork coulometer curves density deposit determined deviation dielectric constant diffusion coefficient double layer effect electrical electrochemical electrochemical potential electrolyte electromotive force equation equivalent experimental experiments faraday function galvanic cell glass gradient H. S. Harned H₂ H₂O Hamer Harned and Owen heat of transfer hydrogen hysteresis Ilkovic increase ions linear measurements metal methanol method molal molal volumes NaCl National Bureau observed obtained Onsager OVERBEEK overpotential overvoltage oxidation partial molal percent Phys plot polarization potassium potential difference reaction reference salt saturated septa shown in figure silver sodium oxalate solid solvent Soret coefficient standard cells sulfate surface t-butanol temperature theory thermodynamic tion transference number tube values Vinal volt voltage Volts weight zero
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Página 65 - express our thanks to the National Research Council of Canada for a grant in aid of this research, and for the
Página 212 - The Physics and Chemistry of the Voyage of HMS Challenger, Vol. II, Part IV, SP LXI.
Página 123 - m is the number of moles of water associated with 1 mole of CdSO 4 in the saturated solution.
Página 212 - [8] HS Harned and BB Owen, The Physical Chemistry of Electrolytic Solutions, 2d ed. (Reinhold Publishing
Página 86 - HS Harned and DM French, Ann. NY Acad. Sci. 46, 267 (1945). HS Harned and RL Nuttall, J. Am. Chem. Soc. 69, 736 (1947).
Página 112 - of the ohm and ampere. Although the German value was not universally accepted, it was a more nearly correct value as later experiments showed. Also, during the years 1893 to 1905, the
Página 212 - G. Tammann, Über die Beziehungen zwischen den inneren Kräften und Eigenschaften der Lösungen,
Página 113 - had proved to be a more nearly correct value. The London Conference still felt, however, that further work was needed and recommended that additional experiments be made.